Bleach Volume 4

The Kurosaki family and some of Ichigo's friends watch a live filming of a TV program about spirit medium Don Kanonji, who unknowingly turns a spirit into a Hollow during the show. Ichigo is forced to clean up the mess, cheering-up the shocked Kanonji. In the following days, Ichigo and Rukia find that many Hollows they have detected have been slain. They soon learn the cause if Uryū Ishida, a classmate of Ichigo's who happens to be one of the remaining Quincies, humans who use spiritual power to destroy hollows. Uryū declares himself an enemy of all Soul Reapers and challenges Ichigo to a competition of hunting hollows.

Quincy Archer Hates You
Contains chapters 26 - 34.