Bleach Volume 41

Now turned into a berserker Hollow, Ichigo attacks Ulquiorra until he is stopped by Uryū just before delivering the final blow. However, Ichigo sees his friends as enemies and stabs Uryū with his zanpakutō. Ulquiorra awakes and interrupts Ichigo from using his cero on Uryū, causing it to backfire on Ichigo and reverting him back to his normal self. Although Ulquiorra demands to have a rematch with Ichigo as he dying from overexerting himself, Ichigo felt such a victory to empty. While his body turns to ash, Ulquiorra remembers his conversations with Orihime and realizes he has grown a heart within himself. Ulquiorra asks Orihime if she is afraid of him, and she replies that she is not. Satisfied with her answer, Ulquiorra dissolves and fades into the winds. At the same time, Chad and Renji enable Rukia to defeat Rudbornn before they find themselves facing a furious Yammy as they learn, despite the 10 tattooe, that he is actually Espada Zero and thus the most powerful of the Espada. Meanwhile, in the fake Karakura Town, Suì-Fēng and Ōmaeda confront Baraggan with the former forced to sacrifice her arm when it was exposed to their opponent's decaying Respira mist after he entered his released state. Hitsugaya is also surpassed by Harribel's released state, and is forced to use the full power from his bankai to counterattack.

Heart
Contains chapters 350 - 358.