Bleach Volume 40

Orihime shields Ichigo from one of Ulquiorra's attacks, but Ichigo requests her to let him fight alone. While the battle continues, Loly Aivirrne and Menoly Mallia approach Orhime with the former intending to harm Orihime. But Yammy Riyalgo suddenly arrives, taking out Menoly and injuring Loly when Ulquiorra refuses to let him fight Ichigo. After being healed by Orihime again, Loly releases her zanpakutō to fight Yammy before he punches her through the wall and lets her fall, seemingly to her death. Yammy was about to attack Orihime when Uryū arrives and uses the mines he had got from Mayuri to drop Yammy all the way to ground level. With Uryū protecting Orihime, Ichigo uses his Hollow powers to confront Ulquiorra. However, after taking their fight to the top of Las Noches to activate his released form, Ulquiorra reveals his Resurrección Segunda Etapa before blowing a hole in Ichigo's chest. A horrified Orihime rushes to Ichigo's lifeless body, only to be blocked by Ulquiorra. Uryū intervenes and attempts a sneak attack yet fails, but he decides to buy Orihime time to heal Ichigo's wounds. Ulquiorra quickly overwhelms him while a distraught Orihime cries out for Ichigo. Orihime's lament breakdown unexpectedly triggers Ichigo to undergo a new transformation.

The Lust
Contains chapters 341 - 349.