Bleach Volume 14

Ichigo awakens after his fight with Kenpachi and learns that Yoruichi is actually a woman. Meanwhile, confronted by Byakuya when he arrived to the prison Ganju faces the Soul Reaper captain and almost got killed as Jūshirō Ukitake, the Captain of Squad Thirteen and Rukia's superior, intervened. Though Ichigo arrives to face Byakuya, Yoruichi knocks Ichigo out and spirits him away. After Ichigo regains consciousness, Yoruichi tells him that she will train him to use his zanpakutō's bankai state. Meanwhile, on their way to Rukia, Orihime and Uryū are attacked by Squad 12's CaptainMayuri Kurotsuchi. A depraved scientist willing to sacrifice his own men, Mayuri reveals that he has experimented on many other Quincies, including Uryū's grandfather Sōken Ishida whose death he was indirectly responsible for.

White Tower Rocks
Contains chapters 116 - 123.